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On the other hand, bonds from C to an element more electronegative than C (the normal situation with most substituents) will have the larger coe cient on C in the s orbital and smaller in the s orbital. Therefore, the two s bonds will experience a weaker interaction than the two s orbitals. This situation is depicted in Figure 4.7b. Carbon and hydrogen have similar electronegativities, and so C C and C H bonds are essentially nonpolarized. However, it does not follow that the intrinsic interaction between two sp n hybridized orbitals (i.e., the C C s bond) is the same as the intrinsic interaction of an sp n orbital and a 1s orbital (the C H bond). Relative C C and C H bond dissociation energies (see, e.g., Table 4.1) suggest that the C C interaction is weaker and that the C C bond will be higher in energy than a C H bond. Conversely, the s orbitals are reversed, that of the C C bond being lower.

When a client application invokes an operation request on one or more services asynchronously, each service returns its response to the application via a completion event. The application must then demultiplex this event to the appropriate handler, such as a function or object, that it uses to process the asynchronous operation response contained in the completion event. To address this problem effectively, we must resolve three forces: A service may not know the original context in which a client application invoked its operations asynchronously. For example, one client might dedicate a separate thread for each operation, whereas another might handle all operations in a single thread. This lack of context makes it hard for a service to know what information its clients need in order to demultiplex and process completion events. Therefore the client application, not the service, should be responsible for determining how completion events are demultiplexed to the handler designated to process them.

When you draw in 3D, you need to edit your models either to make corrections or as part of the construction process. A number of editing commands are exclusively for 3D or have special 3D options. In this section, you explore these special commands and options. Table 24-2 lists most of the regular editing commands and how they re used in 3D drawings. You can use grips on 3D objects, although it s sometimes difficult to visualize in which plane you re moving or stretching an object. You cannot stretch solids, but you can stretch surfaces and wireframes. (If you try to stretch a solid, AutoCAD just moves it.)

A commercial aircraft manufacturer managed production as a programme of projects, with each aircraft treated as a project Each aircraft was costed on a materials and labour basis, using standard-hours for all tasks Production was planned using standard CPA (Critical Path Analysis) deterministic planning tools The basics of most aircraft conformed to a standard production model, but each aircraft involved signi cant variations according to the instrumentation and nishing requirements of the airline or other customers ordering the aircraft Two sources of uncertainty plagued the manager in charge of each aircraft s production: materials might not arrive when they were required; and staff might not be available when they were required, because another aircraft manager might steal them by pleading higher priority or because of illness and staff turnover If materials did not arrive on time they were chased and work rescheduled to use materials and staff that were available.